Compatibility summary
You will need a travel adapter in Pitcairn Islands; plug types used there differ from Spain.
Plug comparison
Spain plug types: C F
Pitcairn Islands plug types: I
There is no common plug type between Spain (C F) and Pitcairn Islands (I). You need a travel adapter.
Voltage comparison
Spain: 230V, 50Hz
Pitcairn Islands: 230V, 50Hz
Voltage difference is within a range many devices tolerate; check your appliance label.